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No, as long as there is liquid phase in the tank the pressure will be the supply pressure (if still connected to the supply tank) or the pressure as defined in the N2O phase diagram. The vent hole is very small and typically you keep the fill going as the tank is venting.Does such vent orifice prevent the tank from reaching atmospheric pressure? Is the hole really very tiny? This does not make a lot of sense to me... looks like even the tiniest hole would bring the fuel tank to normal pressure quite fast.