I got a can of smokeless, but I don't trust it as much (well, I don't trust my ability to pack it as well) as BP. BP has a lower pressure exponent (is that the right term? its been a while), which means that the burn rate is less sensitive to confinement than smokeless. In order to produce a rapid release of gas, smokeless must be under high pressure, such as the conditions in a shell casing at initiation. BP is fairly insensitive to confinement pressure, and will burn quickly whether it's just in the bottom of a tube with no obstruction, or well confined as it would be in a pyrotechnic charge. It means that pouring a gram or two of BP over an ematch which is stuck to the center of a length of wide masking tape, then simply folded over with the edges sealed is sufficient for good ejection.
Why all the cloak and dagger? I walked in and asked for 4F at my "local" gun store (full service - muzzle loaders as well as modern). The clerk asked what I was shooting it in, and I told him I used it for deploying recovery parachutes in high power rocketry. I got a "how 'bout that" a raised eyebrow, and a request for my drivers license so he could fill out the ATF log. Now, it helps that I'm a tall, early 40s white guy who's usually business-casual with a CEO/military officer style haircut. I could easily see how a scruffier character could get less friendly service; though at the place I went, I might not have even gotten the question as to my intended use (I am in Appalachia after all).
Has anyone ever tried "I do Civil War re-enactments?"
Edit: meant to mention: making good black powder is rather difficult. Green powder (unpressed) is simple, but not nearly as energetic - and probably very sooty; not really useful for rocketry. Still, even green powder in a 1-2lb quantity is enough to injure you very seriously should something go wrong near the end of manufacturing.