My question is: Is Polyester webbing a good choice for recovery harnesses, or are there other factors that make it less desirable such as fraying easily or weight or ?
I agree with Mike ('JazzViper') -- polyester (i.e. Dacron) is generally not as good as nylon - for any of various reasons, but the one that I most adhere to is the fact that it is of a 'higher modulus' (i.e. is less stretchy) and, thus, will put more shock loads on the rest of the vehicle. There will be those who remember how much I was 'down' on those glorified rubber bands (i.e. 'bungee') in years past and may think talking about 'stretchy' seems bizarre coming from me. I'm not down on 'stretchy', I'm down on 'weak and inappropriate' for recovery, which bungee is. At least nylon is a rational compromise - *some* stretch, but also high enough tenacity (i.e. strength) to handle the chaos that recovery deployment really is. By that logic, Dacron polyester is not indicated, as it is stiffer and a bad choice for 'shock loading'.
Remember this as well: If your anchorages are robust enough, it *can* handle shock loading -- that's just good design. Remember, the two pieces connected together with whatever 'bridle' you have are *both* "free bodies in space" (i.e. one end is NOT bolted down), and thus, any shock loading will accelerate BOTH parts in a way to dissipate that excess energy (provided anchorages and connecting material is of that level of strength). Don't get too carried away worrying about all that 'hard shock hitting the end'. Design your anchorages in a way that can handle those unforeseen and unplanned loads - use a material capable of those levels of energy and then don't worry.
Dacron *does* have higher resistance to UV radiation - which is why it is almost exclusively used for sails on sailboats (lots of time exposed to the sun). Rocketry recovery is much less exposed (although it surely is exposed during its function interval) - just have to watch for degradation of nylon components and replace when needed.
Tubular nylon is about as good a material for recovery harnesses and other rigging as one can find. Protect it from flame in the 'high heat' areas (Kevlar or Nomex sleeves, etc) - but use it's lower modulus to your advantage.
-- john.