I'm getting ready to mount a pair of rail buttons on a scratchbuild. I was under the impression that one should mount the lower button at or near the center of pressure, and one close to the center of gravity. I realize this is a question with no good answer... but on this rocket, the CP is 9" from the base, and the CG is 16. So if I mounted the buttons at the CG and CP, they would only be 6.5" apart. I suspect that is too close together. The other option is right in front of the rear motor mount centering ring (so it'd be about an inch from the rear of the rocket), and one at the CG.
See picture. The green squares are the tentative rail button placements.

See picture. The green squares are the tentative rail button placements.
