I'll check the local crafts place for that... looking at it though from a flammability standpoint, and since recovery hardware space in my X-wing is minimal, my thinking was that the kevlar may be the better choice?
I had some polished hemp twine and tested it... it's way too flammable. I thought maybe it had been treated with something.
In low power rockets -- some with with packing volumes as small as that in your X-wing -- I've used braided Dacron kite string, Kevlar thread, some kind of lightweight and flexible cotton string that I had lying around in the shop, even cotton embroidery thread. I've burned holes in more than a few canopies but -- so far -- I've never had a shroud line burn through.
There just isn't a lot of surface area on the shroud lines to absorb the radiant energy, or to intercept the hot gas/burning powder, of the ejection charge -- and most of that area is going to be folded up inside the canopy when you pack the chute.
I'd guess that the space blanket mylar from which you cut your canopy will be destroyed by any failure that puts your shroud lines at risk of burning.
One thing to bear in mind. Rocket parachutes are consumables. With care, and good fortune, they last for many launches, but you should certainly expect to replace the parachute at some point.
EDIT --
I don't think I answered the question. There is no reason not to use Kevlar thread, if you've got some handy. I use it to anchor the shock cord to the body in small diameter rockets (where I expect it to be a more-or-less permanent part of the rocket), and have used it for shroud lines. Its expensive and a PITA to cut.