From the NAR . . .
QUOTE :
Safety First - Motor Casing Temperature
Do you know that model rocket motors are permitted to reach a case temperature of 200C (392F) and high power rocket motors are permitted to reach 220C (428F) during or after operation? These limits are in NFPA 1125, Code for the Manufacture of Model Rocket and High Power Rocket Motors. Long-burn-time motors are the types that most often approach these limits.
Obviously, hot melt adhesives are not appropriate for rocket construction, especially adjacent to the motor mount. Second, many 3D printing materials will be severely weakened at maximum motor casing temperatures. Polylactic Acid, or PLA, is a common material for many uses because of its ease of use and low cost. PLA has a maximum service temperature of under 60C. Even the most robust 3D printing materials typically do not have service temperatures over 150C. Finally, epoxy adhesives have a characteristic known as the glass transition temperature or Tg. Epoxies transition from a hard and relatively brittle material to a viscous or rubbery state as temperatures are increased (and revert to the hard state as they cool). The Tg is often less than 75C for many epoxy adhesives.
What does this mean for structural safety in your rocket's design and construction? Try to avoid direct motor case contact with 3D printed structures or epoxy bonds. Use a non-metallic motor tube to provide some thermal insulation. Use epoxies rated for higher temperatures (e.g. Original JB Weld) on bonded metal motor retainers (e.g. Aeropac). And be careful removing casings from your rockets post-flight! Finally, keep in mind that the temperature limits are just that; not every motor casing will get that hot.
Stephen Lubliner,
Safety Committee Chairman
END QUOTE :
Dave F.