I find a strip of vinyl wrap of the right color works a treat for that situation, unless it is a really weird color you are needing. You can get the people who do vinyl decals to cut you strips to the required width. This means you get nice clean lines without paint bleeding under the tape.Hoping that I know how to paint a single silver line on a large rocket...
Electrical tape can also be used at a pinch. Make sure you don't stretch it as you apply it, or it will un-peel from the exposed end.