Actually you could use a BP calculator based on the volume of the airframe, to determine minimum amount of BP to bring the pressure to X psi, and if the Estes or other motors dont produce enough volume of gas, then a stuffer tube could be used to reduce the airframe volume until it does produce enough volume. I yse a BP calculator spread sheet to determine my starting ejection charges for HPR rockets. LPR rockets generally have a ejection charge that cant de easily modified so altering the internal volume would be a safe alternative.
While ground testing LPR isnt usually done, rigging a used motor to be a testing charge holder is easily doable.