What Rex said...
As a teenager growing up, I first read about "double glue joints" in G. Harry Stine's "Handbook of Model Rocketry". Being young and stupid, I thought to myself, "that's a silly way of doing it-- it would take FOREVER waiting on the first layer of glue to dry and then having to apply MORE glue and waiting for that to dry... nuts! I'll just slap the fin to the tube with a thick slobbery layer of yellow wood glue for strength!"
Of course, since I never tried it, I didn't know what I was missing... Decades later as a BAR, I tried the double glue joint once, and was INSTANTLY SOLD on the technique! I apply a thin layer of yellow carpenters wood glue to the fin root and the fin line along which the fin will be glued (after lightly sanding the tube with 220 grit sandpaper to increase adhesion by roughing up the glassine coating). Let that dry for about 20-30 minutes-- doesn't have to be completely dry. Most of the glue and the moisture from it will soak into the balsa and paper tube and it will "tack up" within minutes-- heck in an hour under most conditions it'd be completely dry, but you don't really need it to be (I don't think it will hurt anything if it dries, but very very tacky is good enough (glue thick and very sticky).
To hold the fins and tube while the applied glue dries, I take an old egg carton from the refrigerator and rescue it from the trash can, invert it, and cut slits across the egg cups (foam egg cartons work best) with a sharp hobby knife, cutting across the egg cups perpendicular to the long axis of the carton. This creates "slits" which you can stick the tip edges of the fins into to hold the leading edges up and horizontal while the glue dries on the root edges... I apply a thin layer of glue and spread it evenly into the wood grain of the root edge with a fingertip, and wipe off any excess, leaving a small rounded bead on the fin root. Takes maybe 30 seconds per fin. Same thing with the tube-- a thin, slightly rounded bead, spread thinly and evenly with a fingertip, and wipe off the excess on a paper towel... The tube can sit in the "trough" between the egg cups on the bottom of the egg carton with the glue applied end overhanging the end of the carton to dry, or you can stand the tube upright (glue end up) to tack up...
Once the glue is good and very tacky, apply a second THIN layer of yellow glue, thinly and evenly to the root edge of the fin... spread it thinly with your fingertip, and then carefully align the fin with the tube in the proper location, (both vertically along the tube length, and make sure it's aligned with the long axis of the tube, or correctly canted for rockets that are intended to spin on the way up). I usually put the rear tip of the trailing edge against the tube, make sure it's perpendicular to the tube surface (90 degrees straight out from the tube) and then gently rock the fin forward down onto the tube along the entire root edge length. Press it firmly against the tube and hold it very steady for about 30 seconds... the fin bonds to the tube almost instantly, so if you notice anything awry with the position or alignment, fix it IMMEDIATELY. Hold the fin still for about 30 seconds, and you'll find that the fin is nicely glued to the tube. I usually apply a VERY THIN layer of wood glue to any droplets of wood glue squeezed out from under the fin, and spread it with a fingertip along the root edge to make "mini-fillets" and spread the glue droplets smoothly and evenly along the surface of the tube and fin on both sides. Works great.
As soon as one fin is on, you're ready to move onto the next one... you can do all the fins at once-- on four fin rockets, I usually do them in pairs, and attach an angle-shaped piece of balsa or metal across the fins and clip it on with either clothespins or small clamps, to keep the fins perfectly aligned with one another. Then I do the remaining pair of fins. On three fin rockets, I usually just eyeball it and they come out pretty well aligned.
Set the rocket aside to dry-- I like to stand it up fins up to dry. The same technique works with white glue as well.
It's counterintuitive, but the thinner the glue layer, the stronger the bond, actually... excess glue contributes nothing to strength. So long as it's evenly applied, the joint will be strong. The double-glue joint method allows more glue to soak into the wood pores of the root edge of the fin for excellent strength. Gluing the fin directly to the tube in one pass squeezes most of the glue out from under the fin to either side of it (the fillet areas) and thus prevents much from soaking into the wood grain. How strong is a double-glue joint?? I can say from experience a properly done double-glue joint is stronger than either the paper-strengthened balsa and the paper body tube-- I had a rocket come down one time horizontally and impact sideways under power at high speed on very hard packed clay ground, and the front outer quarter of the fin from the tip inward along the leading edge disintegrated from the force of the impact, despite being papered... the fin finally was stuck in the ground enough that the fin broke loose from the rocket-- it didn't pop off the tube, though, it took the entire outer layer of glassine and underlying paper half the tube's thickness with it... IOW, the glue joint is STRONGER than the material being bonded-- no sense trying to go stronger than that, because either the balsa fin or the tube will fail before the glue joint does! BTW, the rocket was repaired by making a new fin, and building up the damaged area of the tube with another layer of paper glued in its place...
BTW, superglue is handy-- for hardening balsa transitions or nosecones, or even fins (but papering them works better IMHO). It's good for bonding detail parts or small fiddly bits on sci-fi looking rockets or scale rockets... but don't use it to attach fins and structurally-loaded components (like launch lugs, fins, etc.) Cyanoacrylate (super glue or CA) is weak in the shear plane, which is the forces of the rocket landing when the fins hit the ground. CA seals off the pores of balsa so wood glue applications cannot penetrate the wood and bond to it. CA also embrittles over time, leading to an ever weakening joint over time.
There's a number of threads on this topic that I've posted pictures of the process on, and also in many of my build threads-- just do a search for "Dr. Zooch Beta Builds", especially the EFT-1 and Vanguard Eagle threads... the pics and text are in there...
Later and hope this helps! OL JR