bobkrech
Well-Known Member
- Joined
- Jan 20, 2009
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Jim
For mechanical purposes you can measure the swelling of surgical tubing either in a vacuum chamber or by internal pressurization with a compressor as the delta-p is the only environmental parameter that cause the swelling. Naturally the mechanical properties of the specific surgical tubing you use determines the extent od the swelling. The compressor method is also useful as you can measure the bursting pressure of the tubing.
I simply used ProPEP to obtain the BP combustion temperature which was 1712K (2623F). I used the BP formulation in the article I referenced, and normalize the quantities to 1 gram. Room temperature is assume to be 298 K, (25C or 77F)
You can make the hot to cold gas volume ratio vary simply by what you species you use in the calculation. ProPep correctly treats many solid as gases at the combustion temperature however as the gases don't remain that hot for long, I choose to use only the stable species and my exact ratio is 5.74 if I leave out water, and 6.38 if I include it. The hot gas volume generated is 2,103 cc/g (128 cu.in./g) and the room temperature generation is 330 cc/g (20 cu.in./g) where the water is condensed out.
The effective temperature of the ejection gas will be less than the combustion temperature but more than 298K, so that will mean the effective ratio will be less than what I calculated.
Different formulations and different charcoals will give slightly different results, but the results will not be that different.
Bob
For mechanical purposes you can measure the swelling of surgical tubing either in a vacuum chamber or by internal pressurization with a compressor as the delta-p is the only environmental parameter that cause the swelling. Naturally the mechanical properties of the specific surgical tubing you use determines the extent od the swelling. The compressor method is also useful as you can measure the bursting pressure of the tubing.
I simply used ProPEP to obtain the BP combustion temperature which was 1712K (2623F). I used the BP formulation in the article I referenced, and normalize the quantities to 1 gram. Room temperature is assume to be 298 K, (25C or 77F)
You can make the hot to cold gas volume ratio vary simply by what you species you use in the calculation. ProPep correctly treats many solid as gases at the combustion temperature however as the gases don't remain that hot for long, I choose to use only the stable species and my exact ratio is 5.74 if I leave out water, and 6.38 if I include it. The hot gas volume generated is 2,103 cc/g (128 cu.in./g) and the room temperature generation is 330 cc/g (20 cu.in./g) where the water is condensed out.
The effective temperature of the ejection gas will be less than the combustion temperature but more than 298K, so that will mean the effective ratio will be less than what I calculated.
Different formulations and different charcoals will give slightly different results, but the results will not be that different.
Bob