Originally posted by cjl
That thing's rated for 2C, or 200mA current. That's not enough to fire an average E-match, much less estes igniter. Subject it to too much higher current and you're looking at those shorting problems mentioned earlier.
Originally posted by cjl
Oh - it will do it. But, it is more than the rated current by quite a bit, so you can get into some permanent battery damage. That's one of those things you have to be really careful with on a lithium.
You will not get permanent damage for a Li-Po battery by firing an igniter with the referenced Li-Po battery.Originally posted by cjl
Oh - it will do it. But, it is more than the rated current by quite a bit, so you can get into some permanent battery damage. That's one of those things you have to be really careful with on a lithium.
The battery weighs 10 g. Assuming a heat capacity of ~1 J/g-K, the approximate temperature rise in the battery is 13.7J/(10g*1J/g-K)~1.4 C or ~2.5F so it doesn't overheat the battery either.
7.3 Short-circuit
At 20±5, connect batteries anode and cathode by wire
which impedance less than 50m, keep 6h. N
No explosion or fire
Originally posted by bobkrech
For those folks who still believe that Li-Po batteries are an unacceptable risk, please read the attached DOT regulations concerning the air shipment of lithium batteries on passenger aircraft. You should be able to do the math and assess for yourself what DOT and the FAA consider dangerous.
You will not get permanent damage for a Li-Po battery by firing an igniter with the referenced Li-Po battery.
The datasheet states the internal impedence is 0.025 ohms. The resistance of an Estes igniter is ~0.8 ohms. You need 2 amps to fire an Estes igniter so the minimum voltage requirement is V=ri=0.8*2=1.6 volts. A single Li-Po cell generates ~3.7 volt, so and if we consider a low resistance for the wiring the total pyro circuit resistance is in the range of 1-1.25 ohm. The current draw would be i=V/r=3.7/1 to 3.7/1.25 = 3 to 3.7 amps peak, and as you heat the igniter the resistance increases so the current draw decreases. A conventional igniter circuit operates for ~1 second. Triggered for a second, you would be consuming not more than 3.7*3.7=13.7 Joules of energy. The energy capacity of the battery is C =0.1 AH*3.7volts*3600 J/watt-hr=1332 joules. Firing the igniter consumes ~1% of the battery's capacity. The battery weighs 10 g. Assuming a heat capacity of ~1 J/g-K, the approximate temperature rise in the battery is 13.7J/(10g*1J/g-K)~1.4 C or ~2.5F so it doesn't overheat the battery either.
Even if you were to short out the battery, a complete short circuit of the battery would heat the battery to ~-1332J/(10g*1g-K) or ~140C or 250 F above it's starting temperature. It may get hotter internally and bulge the casing or melt the plastic and rupture it, but it won't get hot enough to catch fire. (but it will certaily burn your skin, anything over 50C can give you a burn.) Li-Po batteries have a solid conductive polymer electrolyte, so unlike the flamable liquid electrolyte in the Li-ion batteries in your laptop, Li-Po batteries don't throw out flaming liquid and are quite safe, and the stuff inside the battery is not more chemically dangerous than what's inside other batteries.
For those folks who still believe that Li-Po batteries are an unacceptable risk, please read the attached DOT regulations concerning the air shipment of lithium batteries on passenger aircraft. You should be able to do the math and assess for yourself what DOT and the FAA consider dangerous.
Bob
Most of those crashes are going to damage a LiPo battery, because they have a flimsy foil case.
If 1 in 10 big rockets crash, then there are other problems to start with. Also, if you read what he actually wrote, he stated that they will not catch fire, regardless of what happens to them.
Those are much higher energy, much larger cells than what you would use for rocketry - not really comparable.But what he said is not true. There are all kinds of videos on youtube of LiPo batteries catching on fire. And even if you discount those as fake, I know 2 people who fly RC planes who have had RC batteries catch on fire after a plane crash. One of them had his car burn up, because he put the plane in the trunk after a crash and it caught on fire 20 minutes later. He showed a lot of math, but real world experience says that they do catch on fire. And I do agree that 1 in 10 rockets crashing indicates a problem, but that is a fact as well. These are experienced Level 3 fliers, and occasionally a parachute gets stuck or a charge fails to go off. Often the crashes are enough to smash everything in the altimter bay. I have many first hand pictures - i've even seen a 9v battery get smashed.
So I think the question comes back to - what odds of a forest fire are acceptable?
David
DavidI am not trying to be rude, but it doesn't seem to me that you have been to very many rocket launches. At the launches I go to, about 1 out of 10 big rockets crash. Most of those crashes are going to damage a LiPo battery, because they have a flimsy foil case. Air transport regulations are a whole different thing, because if the plane crashes, the damage is already done. Who cares if the battery catches on fire after the plane crashes? However, with a rocket, our main risk is starting a fire. Have you seen the videos of the battery that is punctured with a nail and catches on fire? How does your math explain that?
I don't know what your level of risk is, but I think that if there is a 1 in 100 or 1 in 500 chance of starting a fire, then that is too high. Over the course of a year, we would easily have that many crashes, and start at least 1 forest fire. In the southeast, there is a drought, and we usually launch in remote areas, so the forest fire could be devastating.
David
David
I don't know your level of expertise in Hazmat Shipping, Safety and Risk Evaluation, Battery Chemistry, and the design and construction of electronic systems for military and aerospace related systems. I have 36 years of professional experience in these areas so I have a fair bit of knowledge in these matters.
I was specifically refering to a 10 g Li-Po battery. All Li-Po batteries sold must meet certain minimum safety test standards. These tests are required internationally for all Li-Po cells before they be sold and shipped, let alone use. The purpose of transportation regulations are not to prevent fires after a crash, but rather to prevent a fire or other situation cause by a hazardous material that will cause a crash.
Safety Test
Test conditions:The following tests must be measured at flowing air and safety protection conditions. All batteries must standard charge and lay 24h.
Item Test Methods Performance
7.1 Over charge - At 20±5℃, charging batteries with constant current 3C5A to voltage5V, then with constant voltage5V till current decline to 0. Stop test till batteries temperature 10℃ lower than max temperature. ==> No explosion or fire
7.2 Over discharge - At 20 ± 5 ℃ , discharge battery with 0.2C5A
continuously 12.5h. ==> No explosion or fire
7.3 - Short-circuit - At 20±5℃, connect batteries anode and cathode by wire which impedance less than 50mΩ, keep 6h. ==> No explosion or fire
7.4 Extrusion - At 20±5℃, put the battery in two parallel steal broad, add pressure 13kN. ==> No explosion or fire
7.5 Thermal shock - Put the battery in the oven. The temperature of the oven is to be raised at 5±1℃ per minute to a temperature of 130±2℃ and remains 60 minutes. ==> No explosion or fire
The bottom line is that there is nothing that can happen in a rocket crash to a 10 grams Li-Po battery that will cause a battery fire.
Bob
7.3 - Short-circuit - At 20±5℃, connect batteries anode and cathode by wire which impedance less than 50mΩ, keep 6h. ==> No explosion or fire
The batteries that blew up my wireless mouse were two AA lithium primary batteries.
ArnoldI received a reply some time back from a person who tested batteries for a living. He descriped some seriously nasty experiments with batteries. From what I understood from his email was that Lithiums can hurt and burn no matter what the size.
The batteries that blew up my wireless mouse were two AA lithium primary batteries. Primary Lithiums cannot do 20C,yet they exploded. It is not pressure that causes LiPoly to burst into flames, it is heat and hydrogen from a external or internal short circuit. If you check online there are several people have had some very bad experience with Lithium batteries catching fire in small flashlights. Again, the probability is low, but one should be aware of the possibility and plan accordingly. Hight probability - no, but if it happens nasty things happen.
David
I don't know your level of expertise in Hazmat Shipping, Safety and Risk Evaluation, Battery Chemistry, and the design and construction of electronic systems for military and aerospace related systems. I have 36 years of professional experience in these areas so I have a fair bit of knowledge in these matters.
I was specifically refering to a 10 g Li-Po battery. All Li-Po batteries sold must meet certain minimum safety test standards. These tests are required internationally for all Li-Po cells before they be sold and shipped, let alone use. The purpose of transportation regulations are not to prevent fires after a crash, but rather to prevent a fire or other situation cause by a hazardous material that will cause a crash.
Safety Test
Test conditions:The following tests must be measured at flowing air and safety protection conditions. All batteries must standard charge and lay 24h.
Item Test Methods Performance
7.1 Over charge - At 20±5℃, charging batteries with constant current 3C5A to voltage5V, then with constant voltage5V till current decline to 0. Stop test till batteries temperature 10℃ lower than max temperature. ==> No explosion or fire
7.2 Over discharge - At 20 ± 5 ℃ , discharge battery with 0.2C5A
continuously 12.5h. ==> No explosion or fire
7.3 - Short-circuit - At 20±5℃, connect batteries anode and cathode by wire which impedance less than 50mΩ, keep 6h. ==> No explosion or fire
7.4 Extrusion - At 20±5℃, put the battery in two parallel steal broad, add pressure 13kN. ==> No explosion or fire
7.5 Thermal shock - Put the battery in the oven. The temperature of the oven is to be raised at 5±1℃ per minute to a temperature of 130±2℃ and remains 60 minutes. ==> No explosion or fire
The bottom line is that there is nothing that can happen in a rocket crash to a 10 grams Li-Po battery that will cause a battery fire.
Bob
PalomarThat is all fine, but what about a 50g or 100g battery that could be used for multiple staged airstarts? I'm sure you are very proud of your chemistry knowledge and experience, but here is a post showing 153 documented cases of LiPo batteries catching fire:
https://www.rcgroups.com/forums/showpost.php?p=1936758&postcount=5
MikeI just have one question for you Bob, how long does it take for a lipo pack to discharge to below the 3V minimum if left alone and not connected to anything?
Thanks,
Mike
Palomar
Did you read these threads? Virtually all of these incidents involved damaged, shorted. overcharged and overdischarged batteries. Many stories I read involved batteries that had been abused, damaged in crashes and by penetrations, and then were knowingly recharged after they had been observed to be damaged and none of these packs had the electronic protection circuitry that is supposed to be part of a LiPo pack.
I'm sorry but LiPo batteries are safe when used properly, it's the users that are careless and cavalier, and some instances down right dangerous. Does this callous attitude mean we should we ban a certain type of battery because a large number of users think they know far more than the manufacturer and blantantly refuse to follow the recommendations of the manufacturer and the battery industry? I think not. Does it mean the the CPSC should ban most currently marked LiPo battery packs? Probably.
Large batteries contain a large amount of stored chemical energy. The impedence of LiPo flatpacks is low and they are capable of delivering high currents for long periods of time. If you drive a screw or knife through such a pack you can easily delivery a kilowatt or more of power into whatever does the penetration and it gets hot. While the battery will not explode, the plastic casing can burn and certainly anything nearby can catch fire: your pants (yes someone threw a damaged battery in the pants pocket, their BMW (yes someone put a damaged battery on the rear seat of their car), the field box (yes someone threw loose LiPo batteries in their field box without protection), their kitchen (yes, someone charged a series/parallel pack without electronic protection unattended in their kitchen), etc., etc., etc.
The electronic battery pack circuitry I am talking about is expensive, probably about $80 for a high power pack, and from what I have seen, hobby R/C LiPo packs don't apparently contain them. Ok, well then please tell me how you can prevent a single cell in a pack from discharge to less than 2.5 volts or charging to more than 4.2 volts, and in the case of a series parallel pack, how you can prevent a highly charged battery from discharging into a discharged battery. The short and simple answer is that you can't.
Hobby R/C flyiers and some rocket folks routinely abuse LiPo batteries and then when they overheat and cause a fire, they cry foul. It's time for them to grow up, take some responsibility, spend the time to read and understand how to properly use LiPo batteries, and stop being so cheap and pay the bucks to make safe battery packs. Doing so isn't rocket science, it's plain old common sense.
Bob
Don't you think these pictures show electronics bays that could have damaged the battery?
David
Sorry, my previous post was missing the best picture ever of a rocket crash. See the altimeter all broken up? Can you at least admit that this could have damaged a LiPo battery?
https://www.nomatech.com/rockets/P6300014.JPG
David
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